[59] “Fast and Selective β‑C−H Borylation of N‑Heterocycles with a Supramolecular Iridium Catalyst: Circumventing Deactivation Pathways and Mechanistic Insights” J. Trouvé, P. Rajeshwaran, M. Tomasini, A. Perennes, T. Roisnel, A. Poater,* R. Gramage-Doria* ACS Catal. 2023, 13, 7715–7729 [link to Article].
[58] “Transition Metal-Catalyzed C-H Bond Functionalization of Diazines and Their Benzo Derivatives” C. Bruneau, R. Gramage-Doria in Transition Metal-Catalyzed C-H Functionalization of Heterocycles (Eds. T. Punniyamurthy, A. Kumar). Wiley-VCH, Weinheim, Germany, 2023, pp 393-434. [link to book Chapter].
[57] “Catalyst Complexity in a Highly Active and Selective Wacker-Type Markovnikov Oxidation of Olefins with a Bioinspired Iron Complex” J. Trouvé, S. Kasemthaveechok, K. Youssef, R. Gramage-Doria* ACS Catal. 2023, 13, 4421–4432 [link to Article].
[56] “Efficient Hydrogen Production at pH 7 in Water with a Heterogeneous Electrocatalyst Based on a Neutral Dimeric Cobalt-Dithiolene Complex” C. Zhang, E. Prignot, O. Jeannin, A. Vacher, D. Dragoe, F. Camerel*, Z. Halime*, R. Gramage-Doria* ACS Catal. 2023, 13, 2367–2373 [link to Article]. Press release by CNRS.
[55] “Destabilizing Predictive Copper-Catalyzed Click Reactions by Remote Interactions with a Zinc-Porphyrin Backbone” J. Trouvé, R. Gramage-Doria* Helvetica Chimica Acta, 2023, 106, e202200191 [link to Article]
[54] “Boosting the activity of Mizoroki-Heck cross-coupling reactions with a supramolecular palladium catalyst favoring remote Zn…pyridine interactions” N. Abuhafez , R. Gramage-Doria* Faraday Discuss., 2023 [link to Article]
[53] “Ruthenium-Catalyzed ortho-C-H Bond Arylation Reactions” C. Bruneau, R. Gramage-Doria in Handbook of CH-Functionalization (Ed. D. Maiti). Wiley-VCH, Weinheim, Germany, 2022. [link to book Chapter].
[52] “Divergent behavior in the chemistry of metal-bis(dithiolene) complexes appended with peripheral aliphatic butyl chains” E. Prignot, C. Zhang, O. Jeannin, Z. Halime*, R. Gramage-Doria*, F. Camerel* Eur. J. Inorg. Chem., 2023, 26, e202200591. [link to article]

[51] “Asymmetric Ruthenium Catalysis Enables Fluorophores with Point Chirality Displaying CPL Properties” Y. Sun, K. Dhbaibi, H. Lauwick, C. Lalli, G. Taupier, Y. Molard, R. Gramage-Doria, S. Dérien, J. Crassous*, M. Achard* Chem. Eur. J. 2023, 29, e202203243. [link to article]

[50] “Electronic, steric and catalytic properties of N-heterocyclic carbenerhodium(I) complexes linked to (metallo)porphyrins” L. Poyac, S. Scoditti, X. Dumail, M. Granier, S. Clément, R. Gramage-Doria, C. H. Devillers, S. Richeter* Chem. Commun. 2022, 58, 13270-13273. [link to Article].
[49] “Precise Control of the Site-Selectivity in Ruthenium-Catalyzed C-H Bond Amidations by Cyclic Amides as Powerful Directing Groups” Y. Yuan*, Q. Lu, X. Zhu, S. Posada-Pérez, M. Solà, A. Poater*, T. Roisnel and R. Gramage-Doria* Org. Chem. Front. 2023, 10, 42-53. [link to Article].
[48] “Iridium-Catalyzed Direct Reductive Amination of Ketones and Secondary Amines: Breaking the Aliphatic Wall” M. Jouffroy,* Thi-Mo Nguyen, M. Cordier, M. Blot, T. Roisnel, R. Gramage-Doria* Chem. Eur. J. 2022, 28, e202201078. [link to Article] Highlighted as Cover Article.
[47] “Unravelling Enzymatic Features in a Supramolecular Iridium Catalyst by Computational Calculations” M. Tomasini, L. Caporaso, J. Trouvé, J. Poater*, R. Gramage-Doria*, A. Poater* Chem. Eur. J. 2022, 28, e202201970 [link to article].
[46] “Sustainable Wacker-Type Oxidations” P. Rajeshwaran, J. Trouvé, K. Youssef, R. Gramage-Doria* Angew. Chem. Int. Ed. 2022, 61, e202211016. [link to Article].