Publications

Independent publications:
[30] “A Supramolecular Palladium Catalyst Displaying Substrate Selectivity by Remote Control”
P. Zardi, T. Roisnel, R. Gramage-Doria*
Chem. Eur. J. accepted, DOI: 10.1002/chem.201804543.
[29] “Merging Transition Metal Catalysis with Phthalimides: a New Entry to Useful Building Blocks”
Y.-C. Yuan, C. Bruneau, R. Gramage-Doria*
Synthesis, 2018, 50, 4216-4228. Invited contribution, Ed: Prof. P. Knochel.
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[28] “Ruthenium-catalyzed C-H Bond Heteroarylation of Triazoles Enabled by a Deconvolution Strategy”
R. Gramage-Doria,* T. Roisnel
Eur. J. Org. Chem. accepted, DOI:10.1002/ejoc.201800843. Invited contribution, COST-CHAOS special issue. Highlighted as Cover.

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[27] “Ruthenium(II)-Catalyzed C-H (Hetero)Arylation of Alkenylic 1,n-Diazines (n = 2, 3, and 4): Scope, Mechanism, and Application in Tandem Hydrogenations”
R. Gramage-Doria,* S. Achelle, C. Bruneau, F. Robin-le Guen, V. Dorcet, T. Roisnel
J. Org. Chem. 2018, 83, 1462-1477.
 jo-2017-03024h_0016
[26] “Unmasking Amides: Ruthenium-Catalyzed Protodecarbonylation of N‑Substituted Phthalimide Derivatives”
Y.-C. Yuan, R. Kamaraj, C. Bruneau, T. Labasque, T. Roisnel, R. Gramage-Doria*
Org. Lett. 2017, 19, 6404-6407. Highlighted in Organic Chemistry Portal.

abstract-ol-2017-03278a_0005

[25] “Palladium-Catalysed Cross-Coupling Reactions Controlled by Noncovalent Zn…N Interactions”
M. Kadri, J. Hou, V. Dorcet, T. Roisnel, L. Bechki, A. Miloudi, C. Bruneau, R. Gramage-Doria*
Chem. Eur. J. 2017, 23, 5033-5043. Highlighted as “Hot Paper” and as Cover article. Press release by CNRS and ChemistryViews.

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[24] “One-pot Directing Group Formation/C-H Bond Functionalization via Copper(I) and Ruthenium(II) Catalysis”
C. Bruneau, R. Gramage-Doria*
Adv. Synth. Catal. 2016, 358, 3847-3856.

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[23] “Nonconventional Supramolecular Self-Assemblies of Zinc(II)-Salphen Building Blocks”
T. Groizard, S. Kahlal, V. Dorcet, T. Roisnel, C. Bruneau, J.-F. Halet,* R. Gramage-Doria*
Eur. J. Inorg. Chem. 2016, 5143-5151.

ejic201600866-toc-0001-m

Mentored publications (Postdoc, PhD and MSc):
[22] “Protonated Bis-1,2,3-triazole as an Anion-Binding Chiral Bronsted Acid for Catalytic Asymmetric Friedel-Crafts Reaction of Indoles with Imines” Y. Furukawa, R. Suzuki, T. Nakashima, R. Gramage-Doria, K. Ohmatsu, T. Ooi* Bull. Chem. Soc. Jpn. 2018, 91, 1252-1257.
[21] “Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage” C. García-Simó, R. Gramage-Doria, S. Raoufmoghaddam, T. Parella, M. Costas,* X. Ribas,* J. N. H. Reek* J. Am. Chem. Soc. 2015, 137, 2680-2687.
[20] “Transition Metal Catalysis in Confined Spaces” S. H. A. M. Leenders, R. Gramage-Doria, B. de Bruin, J. N. H. Reek* Chem. Soc. Rev. 2015, 44, 433-448.
[19] “Gold(I) Catalysis at Extreme Concentrations Inside Self-Assembled Nanospheres” R. Gramage-Doria, J. Hessels, S. H. A. M. Leenders, O. Tröppner, M. Dürr, I. Ivanović-Burmazović, J. N. H. Reek* Angew. Chem. Int. Ed. 2014, 53, 13380-13384.
[18] “Phosphinocyclodextrins as Confining Units for Catalytic Metal Centres. Applications to Carbon-Carbon Bond Forming Reactions” M. Jouffroy, R. Gramage-Doria, D. Sémeril, D. Armspach,* D. Matt,* W. Oberhauser, L. Toupet Beilstein J. Org. Chem. 2014, 10, 2388-2405.
[17] “Confining Phosphanes Derived from Cyclodextrins for Efficient Regio- and Enantioselective Hydroformylation” M. Jouffroy, R. Gramage-Doria, D. Armspach,* D. Sémeril, W. Oberhauser, D. Matt,* L. Toupet Angew. Chem. Int. Ed. 2014, 53, 3937-3940.
[16] “Metallocyclodextrins: Combining Cavitands and Metal Centres” R. Gramage-Doria* ChemistryOpen 2013, 2, 176-179.
[15] “New Endeavors in Gold Catalysis – Size Matters” R. Gramage-Doria,* J. N. H. Reek Angew. Chem. Int. Ed. 2013, 52, 13146-13148.
[14] “Transition Metal Encapsulation within Supramolecular Diphosphine Capsules” T. Besset, R. Gramage-Doria, J. N. H. Reek* Curr. Org. Chem. 2013, 17, 1489-1498.
[13] “Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes” T. Besset,* R. Gramage-Doria, J. N. H. Reek* Angew. Chem. Int. Ed. 2013, 52, 8795-8797.
[12] “Supramolecular Bulky Phosphines Comprising 1,3,5-Triaza-7-phosphaadamantane and Zn(salphen)s: Structural Features and Application in Hydrosilylation Catalysis” D. Anselmo, R. Gramage-Doria, T. Besset, M. V. Escarcega-Bobadilla, G. Salassa, E. C. Escudero-Adan, M. Martinez Belmonte, E. Martin, J. N. H. Reek,* A. W. Kleij* Dalton Trans. 2013, 42, 7595-7603.
[11] “Metalated Cavitands (Calixarenes, Resorcinarenes, Cyclodextrins) with Internal Coordination Sites” R. Gramage-Doria,* D. Armspach,* D. Matt* Coord. Chem. Rev. 2013, 257, 776-816.
[10] “Organocatalysis in Confined Spaces” R. Gramage-Doria, J. N. H. Reek* ChemCatChem 2013, 5, 677-679.
[9] “Supramolecular Ligands in Gold(I) Catalysis” R. Gramage-Doria, R. Bellini, J. Rintjema, J. N. H. Reek* ChemCatChem 2013, 5, 1084-1087.
[8] “Chelating Properties of Permethylated 6A,6D-Dideoxy-6A,6D-bis(1-imidazolyl)cyclodextrins Towards Pt(II) and Ru(III)” C. Egloff, R. Gramage-Doria, M. Jouffroy, D. Armspach,* D. Matt,* L. Toupet C. R. Chimie 2013, 16, 509-514.
[7] “TRANSDIP: a trans-Chelating Ligand Tailor-Made for Probing Unusual Pd(0) and Pd(II) Intermediates” R. Gramage-Doria, D. Armspach,* D. Matt,* L. Toupet Chem. Eur. J. 2012, 18, 10813-10816.
[6] “Non-Conventional Coordination of Cavity-Confined Metal Centres” R. Gramage-Doria, D. Armspach,* D. Matt,* L. Toupet Dalton Trans. 2012, 41, 8786-8796.
[5] “Regioselective Opening of Proximally Sulfato-Capped Cyclodextrins” M. Jouffroy, R. Gramage-Doria, D. Armspach,* D. Matt,* L. Toupet Chem. Commun. 2012, 48, 6028-6030.
[4] “Catalytic Palladium Phosphination: Modular Synthesis of C1-Symmetric Biaryl-Based Diphosphines” L. Bonnafoux, R. Gramage-Doria, F. Colobert, F. R. Leroux* Chem. Eur. J. 2011, 17, 11008-11016.
[3] “Regioselective Double Capping of Cyclodextrin Scaffolds” R. Gramage-Doria, D. Rodriguez-Lucena, D. Armspach,* C. Egloff, M. Jouffroy, D. Matt,* L. Toupet Chem. Eur. J. 2011, 17, 3911-3921.
[2] “Ditopic Binding of Cyclodextrin-Included Ligands in Trigonal Silver(I) Complexes” D. Armspach,* D. Matt,* L. Poorters, R. Gramage-Doria, P. Jones, L. Toupet Polyhedron 2011, 30, 573-578.
[1] “A Cavity-Shaped Diphosphane Displaying “Oschelating” Behavior” R. Gramage-Doria, D. Armspach,* D. Matt,* L. Toupet Angew. Chem. Int. Ed. 2011, 50, 1554-1559.
Patent 1 “Process for preparation of biaryl di- and tri-phosphines as ligands for transition metal-catalyzed asymmetric hydrogenation and coupling reactions by catalytic phosphination of halogenated biaryls” F. R. Leroux, L. Bonnafoux, R. Gramage-Doria, F. Colobert Patent WO 2010-FR52433, FR 2009-58116.