[37] “Base-controlled product switch in the ruthenium-catalyzed protodecarbonylation of phthalimides: a mechanistic study” M. C. D’Alterio, Y.-C. Yuan, C. Bruneau, G. Talarico, R. Gramage-Doria,* A. Poater* Catal. Sci. Technol. 2020, 10, 180-186. [link to article]
[36] “C-H Bond Alkylation of Cyclic Amides with Maleimides via a Site-Selective-Determining Six-Membered Ruthenacycle” Y.-C. Yuan, M. Goujon, C. Bruneau, T. Roisnel, R. Gramage-Doria* J. Org. Chem.2019, 84, 16183-16191. [link to article]
[35] “Site-Selective Ruthenium-Catalyzed C-H Bond Arylations with Boronic Acids: Exploiting Isoindolinones as a Weak Directing Group” Y.-C. Yuan, C. Bruneau, T. Roisnel, R. Gramage-Doria* J. Org. Chem.2019, 84, 12893-12903. [link to article]
[34] “Site-selective Ru-catalyzed C-H bond alkenylation with biologically relevant isoindolinones: a case of catalyst perfomance controlled by subtle stereo-electronic effects of the weak directing group” Y.-C. Yuan, C. Bruneau, T. Roisnel, R. Gramage-Doria* Catal. Sci. Technol.2019, 9, 4711-4717. [link to article]
[32] “Remote Ion-Pair Interactions in Fe-Porphyrin-based Molecular Catalysts for the Hydrogen Evolution Reaction” S. Kasemthaveechok, B. Fabre, G. Loget,* R. Gramage-Doria* Catal. Sci. Technol.2019, 9, 1301-1308. [link to article]
[29] “Merging Transition Metal Catalysis with Phthalimides: a New Entry to Useful Building Blocks” Y.-C. Yuan, C. Bruneau, R. Gramage-Doria* Synthesis, 2018, 50, 4216-4228. [link to article] Invited contribution, Ed: Prof. P. Knochel.
[27] “Ruthenium(II)-Catalyzed C-H (Hetero)Arylation of Alkenylic 1,n-Diazines (n = 2, 3, and 4): Scope, Mechanism, and Application in Tandem Hydrogenations” R. Gramage-Doria,* S. Achelle, C. Bruneau, F. Robin-le Guen, V. Dorcet, T. Roisnel J. Org. Chem. 2018, 83, 1462-1477. [link to article]
[23] “Nonconventional Supramolecular Self-Assemblies of Zinc(II)-Salphen Building Blocks” T. Groizard, S. Kahlal, V. Dorcet, T. Roisnel, C. Bruneau, J.-F. Halet,* R. Gramage-Doria* Eur. J. Inorg. Chem. 2016, 5143-5151. [link to article]
Mentored publications (Postdoc, PhD and MSc):
[22] “Protonated Bis-1,2,3-triazole as an Anion-Binding Chiral Bronsted Acid for Catalytic Asymmetric Friedel-Crafts Reaction of Indoles with Imines” Y. Furukawa, R. Suzuki, T. Nakashima, R. Gramage-Doria, K. Ohmatsu, T. Ooi* Bull. Chem. Soc. Jpn.2018, 91, 1252-1257. [link to article]
[21] “Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage” C. García-Simó, R. Gramage-Doria, S. Raoufmoghaddam, T. Parella, M. Costas,* X. Ribas,* J. N. H. Reek* J. Am. Chem. Soc.2015, 137, 2680-2687. [link to article]
[19] “Gold(I) Catalysis at Extreme Concentrations Inside Self-Assembled Nanospheres” R. Gramage-Doria, J. Hessels, S. H. A. M. Leenders, O. Tröppner, M. Dürr, I. Ivanović-Burmazović, J. N. H. Reek* Angew. Chem. Int. Ed.2014, 53, 13380-13384. [link to article]
[18] “Phosphinocyclodextrins as Confining Units for Catalytic Metal Centres. Applications to Carbon-Carbon Bond Forming Reactions” M. Jouffroy, R. Gramage-Doria, D. Sémeril, D. Armspach,* D. Matt,* W. Oberhauser, L. Toupet Beilstein J. Org. Chem.2014, 10, 2388-2405. [link to article]
[17] “Confining Phosphanes Derived from Cyclodextrins for Efficient Regio- and Enantioselective Hydroformylation” M. Jouffroy, R. Gramage-Doria, D. Armspach,* D. Sémeril, W. Oberhauser, D. Matt,* L. Toupet Angew. Chem. Int. Ed.2014, 53, 3937-3940. [link to article]
[12] “Supramolecular Bulky Phosphines Comprising 1,3,5-Triaza-7-phosphaadamantane and Zn(salphen)s: Structural Features and Application in Hydrosilylation Catalysis” D. Anselmo, R. Gramage-Doria, T. Besset, M. V. Escarcega-Bobadilla, G. Salassa, E. C. Escudero-Adan, M. Martinez Belmonte, E. Martin, J. N. H. Reek,* A. W. Kleij* Dalton Trans.2013, 42, 7595-7603. [link to article]
[8] “Chelating Properties of Permethylated 6A,6D-Dideoxy-6A,6D-bis(1-imidazolyl)cyclodextrins Towards Pt(II) and Ru(III)” C. Egloff, R. Gramage-Doria, M. Jouffroy, D. Armspach,* D. Matt,* L. Toupet C. R. Chimie2013, 16, 509-514. [link to article]
[3] “Regioselective Double Capping of Cyclodextrin Scaffolds” R. Gramage-Doria, D. Rodriguez-Lucena, D. Armspach,* C. Egloff, M. Jouffroy, D. Matt,* L. Toupet Chem. Eur. J.2011, 17, 3911-3921. [link to article]
[2] “Ditopic Binding of Cyclodextrin-Included Ligands in Trigonal Silver(I) Complexes” D. Armspach,* D. Matt,* L. Poorters, R. Gramage-Doria, P. Jones, L. Toupet Polyhedron2011, 30, 573-578. [link to article]
Patent 1 “Process for preparation of biaryl di- and tri-phosphines as ligands for transition metal-catalyzed asymmetric hydrogenation and coupling reactions by catalytic phosphination of halogenated biaryls” F. R. Leroux, L. Bonnafoux, R. Gramage-Doria, F. Colobert Patent WO 2010-FR52433, FR 2009-58116. [link to article]